San Francisco: A team of researchers has for the first time discovered magnetism in the 2-D world of monolayers, or materials that are formed by a single atomic layer.
The findings, published this week in the journal Nature, demonstrate that magnetic properties can exist even in the 2-D realm, opening a world of potential applications, as magnetic materials form the basis of technologies that play increasingly pivotal roles in our lives today, Xinhua news agency reported.
“What we have discovered here is an isolated 2-D material with intrinsic magnetism, and the magnetism in the system is highly robust,” said Xiaodong Xu, a professor of physics and of materials science and engineering at the University of Washington (UW).
“We envision that new information technologies may emerge based on these new 2-D magnets.” Xu and Massachusetts Institute of Technology (MIT) physics professor Pablo Jarillo-Herrero led the international team of researchers who proved that the material, chromium triiodide, or CrI3, has magnetic properties in its monolayer form.
Other groups, including co-author Michael McGuire at the Oak Ridge National Laboratory, which is managed for the US Department of Energy, had previously shown that CrI3, in its multilayered, 3-D, bulk crystal form, is ferromagnetic.
In ferromagnetic materials, the “spins” of constituent electrons, analogous to tiny, subatomic magnets, align in the same direction even without an external magnetic field.
However, no 3-D magnetic substance had previously retained its magnetic properties when thinned down to a single atomic sheet.
Atoms within monolayer materials are considered “functionally” two-dimensional because the electrons can only travel within the atomic sheet, like pieces on a chessboard.
The researchers used a special type of microscopy to detect a signature in CrI3, as in other ferromagnetic materials when a beam of polarised light is reflected off the material`s surface, indicative of intrinsic ferromagnetism in an isolated monolayer.
And surprisingly, in CrI3 flakes that are two layers thick, the telltale optical signature disappeared. This indicates that the electron spins are oppositely aligned to one another, a term known as anti-ferromagnetic ordering. Ferromagnetism returned in three-layer CrI3.